Via Hole Conditioning in Silicon Heterojunction metal Wrap through Solar Cells

Research output: Contribution to journalConference articleContributedpeer-review

Contributors

  • Ingo Dirnstorfer - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Niels Schilling - , Fraunhofer Institute for Material and Beam Technology (Author)
  • Stefan Koerner - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Paul Gierth - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Andreas Waltinger - , Roth and Rau AG (Author)
  • Barbara Leszczynska - , Chair of Semiconductors (Author)
  • Daniel K. Simon - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Jan Gärtner - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Paul M. Jordan - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Thomas Mikolajick - , Chair of Nanoelectronics, NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Ines Dani - , Fraunhofer Institute for Material and Beam Technology (Author)
  • Markus Eberstein - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Lars Rebenklau - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Jens Krause - , Roth and Rau AG (Author)

Abstract

A silicon heterojunction solar cell based on amorphous and crystalline silicon is combined with the metal wrap through technology. In this novel solar cell concept one critical process is the via hole conditioning. Raman measurements reveal that the amorphous silicon emitter layer hardly penetrates the via holes and that thereby the via surface is not fully covered. In the conventional process sequence with via hole formation prior to wet chemical cleaning, the effective carrier lifetime is reduced by about 50 % in the vicinity of the via hole. An improved process sequence is presented, which bases on via holeformation after the thin film depositions. In this sequence, the via hole formation process is crucial for the via surface passivation. The passivation remains poor when applying a 1064 nm laser process. However, very good surface passivation is achieved with a 532 nm laser process. The lifetime reduction was below 20 % at the via hole. The superior performance of the 532 nm laser process is correlated to a smoothervia surfaceand enhanced via sidewall oxidation. Finally, large area SHJ-MWT solar cells based on the optimized via formation process are processed and analyzed.

Details

Original languageEnglish
Pages (from-to)458-463
Number of pages6
JournalEnergy Procedia
Volume77
Publication statusPublished - 2015
Peer-reviewedYes

Conference

Title5th International Conference on Silicon Photovoltaics, SiliconPV 2015
Duration25 - 27 March 2015
CityKonstanz
CountryGermany

External IDs

ORCID /0000-0003-3814-0378/work/142256283

Keywords

ASJC Scopus subject areas

Keywords

  • amorphous silicon, metal wrap through, passivation, recombination, silicon heterojunction