Synthesen, Kristallstrukturen und Drillingsbildung der Cluster-Trimere Bi2[PtBi6Br12]3 und Bi 2[PtBi6I12]3

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Melting reactions of Bi with Pt and BiX3 (X = Br, I) yield shiny black, air insensitive crystals of the subhalides Bi2[PtBi 6X12]. Bi2[PtBi6Br 12]3 crystallizes in the monoclinic space group C2/m with lattice parameters a = 1617.6(2) pm, b = 1488.5(1) pm, c = 1752.4(2) pm, and β = 110.85(4)°. Bi2[PtBi6I12] 3 adopts the triclinic space group C1 with pseudo-monoclinic lattice parameters a = 1711.2(2) pm, b = 1585.1(1) pm, c = 1865.7(2) pm, and α = 90°, β = 111.15(4)°, γ = 90°. The two homoeotypic compounds consist of cuboctahedral [Pt-IIBiII 6X-I12]2- clusters that are concatenated into linear trimers by BiIII atoms. The ordered distribution of BiIII atoms destroys the inherent threefold rotation axes in the packing of cluster anions. As a consequence of the pseudosymmetry the crystals are triple twinned along [201]. Due to different orientations of the cluster trimers there are two BiII·X inter-cluster bridges per BiII atom in Bi2[PtBi6Br 12]3 but only one bridge in Bi2[PtBi 6I12]3. The structure of the iodine compound can be deduced from the NaCl structure type, leaving 37 of 96 atomic positions unoccupied. The arrangement of the cuboctahedral clusters follows the motif of a body-centered cubic packing.

Translated title of the contribution
Syntheses, crystal structures, and triple twinning of the cluster trimers Bi2[PtBi6Br12]3 and Bi 2[PtBi6I12]3

Details

Original languageGerman
Pages (from-to)423-430
Number of pages8
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume634
Issue number3
Publication statusPublished - Mar 2008
Peer-reviewedYes

External IDs

ORCID /0000-0002-2391-6025/work/166325849

Keywords

ASJC Scopus subject areas

Keywords

  • Bismuth, Cluster compounds, Platinum, Pseudosymmetry, Twinning