Synthesen, Kristallstrukturen und Drillingsbildung der Cluster-Trimere Bi2[PtBi6Br12]3 und Bi 2[PtBi6I12]3

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

Melting reactions of Bi with Pt and BiX3 (X = Br, I) yield shiny black, air insensitive crystals of the subhalides Bi2[PtBi 6X12]. Bi2[PtBi6Br 12]3 crystallizes in the monoclinic space group C2/m with lattice parameters a = 1617.6(2) pm, b = 1488.5(1) pm, c = 1752.4(2) pm, and β = 110.85(4)°. Bi2[PtBi6I12] 3 adopts the triclinic space group C1 with pseudo-monoclinic lattice parameters a = 1711.2(2) pm, b = 1585.1(1) pm, c = 1865.7(2) pm, and α = 90°, β = 111.15(4)°, γ = 90°. The two homoeotypic compounds consist of cuboctahedral [Pt-IIBiII 6X-I12]2- clusters that are concatenated into linear trimers by BiIII atoms. The ordered distribution of BiIII atoms destroys the inherent threefold rotation axes in the packing of cluster anions. As a consequence of the pseudosymmetry the crystals are triple twinned along [201]. Due to different orientations of the cluster trimers there are two BiII·X inter-cluster bridges per BiII atom in Bi2[PtBi6Br 12]3 but only one bridge in Bi2[PtBi 6I12]3. The structure of the iodine compound can be deduced from the NaCl structure type, leaving 37 of 96 atomic positions unoccupied. The arrangement of the cuboctahedral clusters follows the motif of a body-centered cubic packing.

Details

OriginalspracheDeutsch
Seiten (von - bis)423-430
Seitenumfang8
FachzeitschriftZeitschrift fur Anorganische und Allgemeine Chemie
Jahrgang634
Ausgabenummer3
PublikationsstatusVeröffentlicht - März 2008
Peer-Review-StatusJa

Externe IDs

ORCID /0000-0002-2391-6025/work/166325849

Schlagworte

ASJC Scopus Sachgebiete

Schlagwörter

  • Bismuth, Cluster compounds, Platinum, Pseudosymmetry, Twinning