Stacked topological insulator built from bismuth-based graphene sheet analogues
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Commonly, materials are classified as either electrical conductors or insulators. The theoretical discovery of topological insulators has fundamentally challenged this dichotomy. In a topological insulator, the spin-orbit interaction generates a non-trivial topology of the electronic band structure dictating that its bulk is perfectly insulating, whereas its surface is fully conducting. The first topological insulator candidate material put forward - graphene - is of limited practical use because its weak spin-orbit interactions produce a bandgap of ∼ 0.01 K. Recent reexaminations of Bi 2Se3 and Bi2Te3, however, have firmly categorized these materials as strong three-dimensional topological insulators. We have synthesized the first bulk material belonging to an entirely different, weak, topological class, built from stacks of two-dimensional topological insulators: Bi14Rh3I9. Its Bi-Rh sheets are graphene analogues, but with a honeycomb net composed of RhBi 8 cubes rather than carbon atoms. The strong bismuth-related spin-orbit interaction renders each graphene-like layer a topological insulator with a 2,400 K bandgap.
Details
Original language | English |
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Pages (from-to) | 422-425 |
Number of pages | 4 |
Journal | Nature materials |
Volume | 12 |
Issue number | 5 |
Publication status | Published - May 2013 |
Peer-reviewed | Yes |
External IDs
ORCID | /0000-0002-2391-6025/work/159171898 |
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