Stacked topological insulator built from bismuth-based graphene sheet analogues

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Bertold Rasche - , Chair of Inorganic Chemistry II (Author)
  • Anna Isaeva - , Chair of Inorganic Chemistry II (Author)
  • Michael Ruck - , Chair of Inorganic Chemistry II, Max Planck Institute for Chemical Physics of Solids (Author)
  • Sergey Borisenko - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Volodymyr Zabolotnyy - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Bernd Büchner - , Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Klaus Koepernik - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Carmine Ortix - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Manuel Richter - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Jeroen Van Den Brink - , Chair of Solid State Theory, Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

Commonly, materials are classified as either electrical conductors or insulators. The theoretical discovery of topological insulators has fundamentally challenged this dichotomy. In a topological insulator, the spin-orbit interaction generates a non-trivial topology of the electronic band structure dictating that its bulk is perfectly insulating, whereas its surface is fully conducting. The first topological insulator candidate material put forward - graphene - is of limited practical use because its weak spin-orbit interactions produce a bandgap of ∼ 0.01 K. Recent reexaminations of Bi 2Se3 and Bi2Te3, however, have firmly categorized these materials as strong three-dimensional topological insulators. We have synthesized the first bulk material belonging to an entirely different, weak, topological class, built from stacks of two-dimensional topological insulators: Bi14Rh3I9. Its Bi-Rh sheets are graphene analogues, but with a honeycomb net composed of RhBi 8 cubes rather than carbon atoms. The strong bismuth-related spin-orbit interaction renders each graphene-like layer a topological insulator with a 2,400 K bandgap.

Details

Original languageEnglish
Pages (from-to)422-425
Number of pages4
JournalNature materials
Volume12
Issue number5
Publication statusPublished - May 2013
Peer-reviewedYes

External IDs

ORCID /0000-0002-2391-6025/work/159171898