Stacked topological insulator built from bismuth-based graphene sheet analogues

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

Commonly, materials are classified as either electrical conductors or insulators. The theoretical discovery of topological insulators has fundamentally challenged this dichotomy. In a topological insulator, the spin-orbit interaction generates a non-trivial topology of the electronic band structure dictating that its bulk is perfectly insulating, whereas its surface is fully conducting. The first topological insulator candidate material put forward - graphene - is of limited practical use because its weak spin-orbit interactions produce a bandgap of ∼ 0.01 K. Recent reexaminations of Bi 2Se3 and Bi2Te3, however, have firmly categorized these materials as strong three-dimensional topological insulators. We have synthesized the first bulk material belonging to an entirely different, weak, topological class, built from stacks of two-dimensional topological insulators: Bi14Rh3I9. Its Bi-Rh sheets are graphene analogues, but with a honeycomb net composed of RhBi 8 cubes rather than carbon atoms. The strong bismuth-related spin-orbit interaction renders each graphene-like layer a topological insulator with a 2,400 K bandgap.

Details

OriginalspracheEnglisch
Seiten (von - bis)422-425
Seitenumfang4
FachzeitschriftNature materials
Jahrgang12
Ausgabenummer5
PublikationsstatusVeröffentlicht - Mai 2013
Peer-Review-StatusJa

Externe IDs

ORCID /0000-0002-2391-6025/work/159171898