Stability and performance of heterogeneous anode assemblies of silicon nanowires on carbon meshes for lithium-sulfur battery applications

Research output: Contribution to book/Conference proceedings/Anthology/ReportConference contributionContributedpeer-review

Contributors

  • Andreas Krause - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Jan Brueckner - , Fraunhofer Institute for Material and Beam Technology (Author)
  • Susanne Doerfler - , Fraunhofer Institute for Material and Beam Technology (Author)
  • Florian M. Wisser - , Chair of Inorganic Chemistry I (Author)
  • Holger Althues - , Fraunhofer Institute for Material and Beam Technology (Author)
  • Matthias Grube - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Jan R. Martin - , TUD Dresden University of Technology (Author)
  • Julia Grothe - , Chair of Inorganic Chemistry I (Author)
  • Thomas Mikolajick - , Center for Advancing Electronics Dresden (cfaed), Chair of Nanoelectronics, NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Walter M. Weber - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)

Abstract

Si is a promising anode material for Li storage due to its high theoretical specific capacity surpassing 4200 Ah/kg. Si based anodes exhibit an extreme instability upon electrochemical incorporation of Li given the accompanied large volume expansion of about 400%. We show innovative anode assemblies composed of a forest of free standing Si nanowires conformally integrated on carbon meshes. The morphology of silicon nanowires allows a volume expansion and compression lowering strain incorporation. In this paper, we demonstrate the utilization of SiNW grown on top of a current collector made of a carbon fiber network. This leads to an increase of stability of Si with a remaining effective capacitance above 2000 Ah/kg(Si) after 225 full charge/discharge cycles. This is significantly better compared to previous results shown in literature. The anodes are fabricated by a simple and inexpensive method promising for a transfer into industrial integration.

Details

Original languageEnglish
Title of host publicationSemiconductor Nanowires - Growth, Physics, Devices and Applications
EditorsG. Koblmueller
PublisherMaterials Research Society
Pages19-24
Number of pages6
ISBN (electronic)9781510806276
Publication statusPublished - 2015
Peer-reviewedYes

Publication series

SeriesMaterials Research Society Symposium Proceedings
Volume1751
ISSN0272-9172

Conference

Title2014 MRS Fall Meeting
Duration30 November - 5 December 2014
CityBoston
CountryUnited States of America

External IDs

ORCID /0000-0003-3814-0378/work/142256285