Stability and performance of heterogeneous anode assemblies of silicon nanowires on carbon meshes for lithium-sulfur battery applications
Research output: Contribution to book/Conference proceedings/Anthology/Report › Conference contribution › Contributed › peer-review
Contributors
Abstract
Si is a promising anode material for Li storage due to its high theoretical specific capacity surpassing 4200 Ah/kg. Si based anodes exhibit an extreme instability upon electrochemical incorporation of Li given the accompanied large volume expansion of about 400%. We show innovative anode assemblies composed of a forest of free standing Si nanowires conformally integrated on carbon meshes. The morphology of silicon nanowires allows a volume expansion and compression lowering strain incorporation. In this paper, we demonstrate the utilization of SiNW grown on top of a current collector made of a carbon fiber network. This leads to an increase of stability of Si with a remaining effective capacitance above 2000 Ah/kg(Si) after 225 full charge/discharge cycles. This is significantly better compared to previous results shown in literature. The anodes are fabricated by a simple and inexpensive method promising for a transfer into industrial integration.
Details
Original language | English |
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Title of host publication | Semiconductor Nanowires - Growth, Physics, Devices and Applications |
Editors | G. Koblmueller |
Publisher | Materials Research Society |
Pages | 19-24 |
Number of pages | 6 |
ISBN (electronic) | 9781510806276 |
Publication status | Published - 2015 |
Peer-reviewed | Yes |
Publication series
Series | Materials Research Society Symposium Proceedings |
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Volume | 1751 |
ISSN | 0272-9172 |
Conference
Title | 2014 MRS Fall Meeting |
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Duration | 30 November - 5 December 2014 |
City | Boston |
Country | United States of America |
External IDs
ORCID | /0000-0003-3814-0378/work/142256285 |
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