Stability and performance of heterogeneous anode assemblies of silicon nanowires on carbon meshes for lithium-sulfur battery applications
Publikation: Beitrag in Buch/Konferenzbericht/Sammelband/Gutachten › Beitrag in Konferenzband › Beigetragen › Begutachtung
Beitragende
Abstract
Si is a promising anode material for Li storage due to its high theoretical specific capacity surpassing 4200 Ah/kg. Si based anodes exhibit an extreme instability upon electrochemical incorporation of Li given the accompanied large volume expansion of about 400%. We show innovative anode assemblies composed of a forest of free standing Si nanowires conformally integrated on carbon meshes. The morphology of silicon nanowires allows a volume expansion and compression lowering strain incorporation. In this paper, we demonstrate the utilization of SiNW grown on top of a current collector made of a carbon fiber network. This leads to an increase of stability of Si with a remaining effective capacitance above 2000 Ah/kg(Si) after 225 full charge/discharge cycles. This is significantly better compared to previous results shown in literature. The anodes are fabricated by a simple and inexpensive method promising for a transfer into industrial integration.
Details
Originalsprache | Englisch |
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Titel | Semiconductor Nanowires - Growth, Physics, Devices and Applications |
Redakteure/-innen | G. Koblmueller |
Herausgeber (Verlag) | Materials Research Society |
Seiten | 19-24 |
Seitenumfang | 6 |
ISBN (elektronisch) | 9781510806276 |
Publikationsstatus | Veröffentlicht - 2015 |
Peer-Review-Status | Ja |
Publikationsreihe
Reihe | Materials Research Society Symposium Proceedings |
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Band | 1751 |
ISSN | 0272-9172 |
Konferenz
Titel | 2014 MRS Fall Meeting |
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Dauer | 30 November - 5 Dezember 2014 |
Stadt | Boston |
Land | USA/Vereinigte Staaten |
Externe IDs
ORCID | /0000-0003-3814-0378/work/142256285 |
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