Stability and performance of heterogeneous anode assemblies of silicon nanowires on carbon meshes for lithium-sulfur battery applications

Publikation: Beitrag in Buch/Konferenzbericht/Sammelband/GutachtenBeitrag in KonferenzbandBeigetragenBegutachtung

Beitragende

Abstract

Si is a promising anode material for Li storage due to its high theoretical specific capacity surpassing 4200 Ah/kg. Si based anodes exhibit an extreme instability upon electrochemical incorporation of Li given the accompanied large volume expansion of about 400%. We show innovative anode assemblies composed of a forest of free standing Si nanowires conformally integrated on carbon meshes. The morphology of silicon nanowires allows a volume expansion and compression lowering strain incorporation. In this paper, we demonstrate the utilization of SiNW grown on top of a current collector made of a carbon fiber network. This leads to an increase of stability of Si with a remaining effective capacitance above 2000 Ah/kg(Si) after 225 full charge/discharge cycles. This is significantly better compared to previous results shown in literature. The anodes are fabricated by a simple and inexpensive method promising for a transfer into industrial integration.

Details

OriginalspracheEnglisch
TitelSemiconductor Nanowires - Growth, Physics, Devices and Applications
Redakteure/-innenG. Koblmueller
Herausgeber (Verlag)Materials Research Society
Seiten19-24
Seitenumfang6
ISBN (elektronisch)9781510806276
PublikationsstatusVeröffentlicht - 2015
Peer-Review-StatusJa

Publikationsreihe

ReiheMaterials Research Society Symposium Proceedings
Band1751
ISSN0272-9172

Konferenz

Titel2014 MRS Fall Meeting
Dauer30 November - 5 Dezember 2014
StadtBoston
LandUSA/Vereinigte Staaten

Externe IDs

ORCID /0000-0003-3814-0378/work/142256285