Nanoscale reconstruction of surface crystallography from three-dimensional polarization distribution in ferroelectric barium-titanate ceramics

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • L. M. Eng - , Chair of Experimental Physics / Photophysics (Author)
  • H. J. Güntherodt - , University of Basel (Author)
  • G. A. Schneider - , Hamburg University of Technology (Author)
  • U. Köpke - , Hamburg University of Technology (Author)
  • J. Muñoz Saldaña - , Hamburg University of Technology (Author)

Abstract

The three-dimensional orientation of polarization vectors at the surface of ferroelectric barium-titanate (BaTiO3) ceramics is evaluated using voltage-modulated scanning force microscopy (SFM). By applying an ac voltage to the conductive SFM tip, we measure the relative amount of the three orthogonal components Px, Py, and Pz, of the polarization vector at any surface point. The measured polarization orientation together with the actual domain-wall orientation allows a precise reconstruction of the crystallographic orientation of the investigated grains down to a 40 nm resolution. Excellent agreement is obtained when comparing this orientation with the crystallographic reconstruction revealed by etch patterns from the sample surface topography. We show that the surface topography manifests a domain structure, which was present in the past, while the actual ferroelectric domain configuration is revealed by the modulation technique.

Details

Original languageEnglish
Pages (from-to)233-235
Number of pages3
JournalApplied physics letters
Volume74
Issue number2
Publication statusPublished - 11 Jan 1999
Peer-reviewedYes

External IDs

ORCID /0000-0002-2484-4158/work/158768112

Keywords

ASJC Scopus subject areas