Forming-free resistive switching in multiferroic BiFeO3 thin films with enhanced nanoscale shunts

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Xin Ou - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Yao Shuai - , University of Electronic Science and Technology of China (Author)
  • Wenbo Luo - , University of Electronic Science and Technology of China (Author)
  • Pablo F. Siles - , Chemnitz University of Technology, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Reinhard Kögler - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Jan Fiedler - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Helfried Reuther - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Shengqiang Zhou - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • René Hübner - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Stefan Facsko - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Manfred Helm - , Chair of Semiconductor Spectroscopy, Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Thomas Mikolajick - , Institute of Semiconductors and Microsystems, Chair of Nanoelectronics (Author)
  • Oliver G. Schmidt - , Chemnitz University of Technology, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Heidemarie Schmidt - , Chemnitz University of Technology (Author)

Abstract

A controlled shunting of polycrystalline oxide thin films on the nanometer length scale opens the door to significantly modify their transport properties. In this paper, the low energy Ar+ irradiation induced shunting effect of forming-free, non-volatile resistive switching in polycrystalline BiFeO 3 thin film capacitor-like structures with macroscopic bottom and top contacts was investigated. Oxygen atoms at the BiFeO3 surface are preferentially sputtered by Ar+ ion irradiation and oxygen vacancies and a metallic Bi phase are formed at the surface of the BiFeO3 thin film before deposition of the top contacts. A phenomenological model is that of nanoscale shunt resistors formed in parallel to the actual BiFeO3 thin film capacitor-like structure. This model fits the noticeable increase of the retention stability and current density after irradiation. The formation of stable and conductive shunts is further evidenced by conductive atomic force microscopy measurements.

Details

Original languageEnglish
Pages (from-to)12764-12771
Number of pages8
JournalACS Applied Materials and Interfaces
Volume5
Issue number23
Publication statusPublished - 11 Dec 2013
Peer-reviewedYes

External IDs

ORCID /0000-0003-3814-0378/work/142256308

Keywords

ASJC Scopus subject areas

Keywords

  • Ar irradiation, BiFeO, current retention, oxygen vacancy, resistive switching, shunting