Forming-free resistive switching in multiferroic BiFeO3 thin films with enhanced nanoscale shunts

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Xin Ou - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Autor:in)
  • Yao Shuai - , University of Electronic Science and Technology of China (Autor:in)
  • Wenbo Luo - , University of Electronic Science and Technology of China (Autor:in)
  • Pablo F. Siles - , Technische Universität Chemnitz, Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (Autor:in)
  • Reinhard Kögler - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Autor:in)
  • Jan Fiedler - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Autor:in)
  • Helfried Reuther - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Autor:in)
  • Shengqiang Zhou - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Autor:in)
  • René Hübner - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Autor:in)
  • Stefan Facsko - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Autor:in)
  • Manfred Helm - , Professur für Spektroskopie in der Halbleiterphysik (gB/HZDR), Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Autor:in)
  • Thomas Mikolajick - , Institut für Halbleiter- und Mikrosystemtechnik (IHM), Professur für Nanoelektronik (Autor:in)
  • Oliver G. Schmidt - , Technische Universität Chemnitz, Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (Autor:in)
  • Heidemarie Schmidt - , Technische Universität Chemnitz (Autor:in)

Abstract

A controlled shunting of polycrystalline oxide thin films on the nanometer length scale opens the door to significantly modify their transport properties. In this paper, the low energy Ar+ irradiation induced shunting effect of forming-free, non-volatile resistive switching in polycrystalline BiFeO 3 thin film capacitor-like structures with macroscopic bottom and top contacts was investigated. Oxygen atoms at the BiFeO3 surface are preferentially sputtered by Ar+ ion irradiation and oxygen vacancies and a metallic Bi phase are formed at the surface of the BiFeO3 thin film before deposition of the top contacts. A phenomenological model is that of nanoscale shunt resistors formed in parallel to the actual BiFeO3 thin film capacitor-like structure. This model fits the noticeable increase of the retention stability and current density after irradiation. The formation of stable and conductive shunts is further evidenced by conductive atomic force microscopy measurements.

Details

OriginalspracheEnglisch
Seiten (von - bis)12764-12771
Seitenumfang8
FachzeitschriftACS Applied Materials and Interfaces
Jahrgang5
Ausgabenummer23
PublikationsstatusVeröffentlicht - 11 Dez. 2013
Peer-Review-StatusJa

Externe IDs

ORCID /0000-0003-3814-0378/work/142256308

Schlagworte

ASJC Scopus Sachgebiete

Schlagwörter

  • Ar irradiation, BiFeO, current retention, oxygen vacancy, resistive switching, shunting