Voltage Programmable Pyroelectric Sensors with ZrO2-based Antiferroelectrics
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
The physics operating at the nanometer scale in antiferroelectric devices has provided a pathway for new voltage programmable, passively operated pyroelectric sensors. Zr1-xHfxO2 thin films of 8 and 6 nm thickness are incorporated into workfunction engineered capacitors to provide non-volatile switching of pyroelectric and non-pyroelectric states. The different operating principles of the voltage control of the pyroelectric response between ferroelectrics and the antiferroelectric pyroelectric switches are demonstrated. Simple ± 2.5 V voltage pulses can turn the pyroelectric effect on and off in the workfunction engineered ZrO2-based thin film antiferroelectric capacitors. Zero-field pyroelectric coefficients with magnitudes of up to 108 μC m-2 K-1 were measured in the pyroelectric on-state. Hf-doping lowered the endurance of the nonpolar off-state with switching cycles, where degradation was observed to begin at 104 – 106 cycles. The loss of the nonpolar state and the convergence of the on-state and off-state pyroelectric coefficients after 1010 cycles was attributable to an irreversible phase transition to the ferroelectric phase, in agreement with the ‘wake-up’ phenomenon widely observed in HfO2 and ZrO2-based films. Undoped ZrO2 exhibited the best cycling endurance with an off-state pyroelectric coefficient magnitude of 10.3 μC m-2 K-1 after 2*1010 cycles, demonstrating the potential for long lifetime pyroelectric devices. The robust demonstration of the operating principles and performance of these programmable antiferroelectric pyroelectric sensors establishes a new design framework for high speed and reconfigurable pyroelectric systems.
Details
Original language | English |
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Pages (from-to) | 12050-12057 |
Number of pages | 8 |
Journal | IEEE sensors journal |
Volume | 24 |
Issue number | 8 |
Publication status | Published - 15 Apr 2024 |
Peer-reviewed | Yes |
External IDs
Mendeley | b67e04c9-5d94-3095-89ba-aa8c3aae0f9e |
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ORCID | /0000-0003-3814-0378/work/159172302 |
Keywords
ASJC Scopus subject areas
Keywords
- Antiferroelectrics, Phase Transitions, Pyroelectric Sensors, Reconfigurable Devices, ZrO<sub xmlns:ali="http://www.niso.org/schemas/ali/1.0/" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">2</sub>, Antiferroelectrics (AFEs), ZrO2, pyroelectric sensors, reconfigurable devices, phase transitions