Vibrational heating in single-molecule switches: an energy-dependent density-of-states approach

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

In recent experiments, it has been shown that the switching rate of single-molecule switches can show a rather complicated dependence on the applied bias voltage. Here, we discuss a minimal model which describes the switching process in terms of inelastic scattering processes of the tunneling electron by specific molecular vibrations. One important point is the introduction of an energy-dependent electronic density of states around the Fermi energy. The influence of different model parameters on the switching rate is studied and we show that the inclusion of a variable density of states allows us to understand the non-monotonic behavior of the switching rate observed in some experiments.

Details

Original languageEnglish
Article number394003
Number of pages6
JournalJournal of Physics: Condensed Matter
Volume24
Issue number39
Publication statusPublished - 3 Oct 2012
Peer-reviewedYes

External IDs

Scopus 84866260066
WOS 000308861500004
PubMed 22964829
ORCID /0000-0001-8121-8041/work/142240822

Keywords

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Keywords

  • Scanning tunneling microscope, Atom-transfer, Conductance, Junction, Azobenzene, Isomerization, Manipulation, Adsorbate, Stm