Vibrational heating in single-molecule switches: an energy-dependent density-of-states approach
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
In recent experiments, it has been shown that the switching rate of single-molecule switches can show a rather complicated dependence on the applied bias voltage. Here, we discuss a minimal model which describes the switching process in terms of inelastic scattering processes of the tunneling electron by specific molecular vibrations. One important point is the introduction of an energy-dependent electronic density of states around the Fermi energy. The influence of different model parameters on the switching rate is studied and we show that the inclusion of a variable density of states allows us to understand the non-monotonic behavior of the switching rate observed in some experiments.
Details
Originalsprache | Englisch |
---|---|
Aufsatznummer | 394003 |
Seitenumfang | 6 |
Fachzeitschrift | Journal of Physics: Condensed Matter |
Jahrgang | 24 |
Ausgabenummer | 39 |
Publikationsstatus | Veröffentlicht - 3 Okt. 2012 |
Peer-Review-Status | Ja |
Externe IDs
Scopus | 84866260066 |
---|---|
WOS | 000308861500004 |
PubMed | 22964829 |
ORCID | /0000-0001-8121-8041/work/142240822 |
Schlagworte
DFG-Fachsystematik nach Fachkollegium
Fächergruppen, Lehr- und Forschungsbereiche, Fachgebiete nach Destatis
Schlagwörter
- Scanning tunneling microscope, Atom-transfer, Conductance, Junction, Azobenzene, Isomerization, Manipulation, Adsorbate, Stm