Vibrational heating in single-molecule switches: an energy-dependent density-of-states approach

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

In recent experiments, it has been shown that the switching rate of single-molecule switches can show a rather complicated dependence on the applied bias voltage. Here, we discuss a minimal model which describes the switching process in terms of inelastic scattering processes of the tunneling electron by specific molecular vibrations. One important point is the introduction of an energy-dependent electronic density of states around the Fermi energy. The influence of different model parameters on the switching rate is studied and we show that the inclusion of a variable density of states allows us to understand the non-monotonic behavior of the switching rate observed in some experiments.

Details

OriginalspracheEnglisch
Aufsatznummer394003
Seitenumfang6
FachzeitschriftJournal of Physics: Condensed Matter
Jahrgang24
Ausgabenummer39
PublikationsstatusVeröffentlicht - 3 Okt. 2012
Peer-Review-StatusJa

Externe IDs

Scopus 84866260066
WOS 000308861500004
PubMed 22964829
ORCID /0000-0001-8121-8041/work/142240822

Schlagworte

DFG-Fachsystematik nach Fachkollegium

Fächergruppen, Lehr- und Forschungsbereiche, Fachgebiete nach Destatis

Schlagwörter

  • Scanning tunneling microscope, Atom-transfer, Conductance, Junction, Azobenzene, Isomerization, Manipulation, Adsorbate, Stm