In search of a suitable single-source precursor for the deposition of nanostructured PbS thin films at moderate temperatures under ambient conditions, we have synthesized the ligand N-(thiomorpholine-4-carbothioyl)benzamide and its corresponding lead(II) complex. The structures of both compounds were determined by single-crystal X-ray diffraction. In the complex, two ligands coordinate to a lead(II) atom in hemi-directed geometry through S and O atoms. Secondary intermolecular Pb⋅⋅⋅S interactions group the complexes into pairs. As bulk powders, both the ligand and complex show nominal composition and purity as evidenced by elemental analysis, ¹H NMR and IR spectroscopy. Thermal analysis of the lead(II) complex was carried out to understand its thermal decomposition behaviour for establishing a thin film fabrication protocol. Thin films of phase-pure PbS were fabricated using this new molecular precursor at the comparatively low annealing temperature of 250 °C. The film showed nanoparticles with cuboidal morphology and a blue-shifted optical absorption.