The Role of Electronic and Phononic Excitation in the Optical Response of Monolayer WS2 after Ultrafast Excitation

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Claudia Ruppert - , Columbia University, Dortmund University of Technology (Author)
  • Alexey Chernikov - , Columbia University, University of Regensburg (Author)
  • Heather M. Hill - , Columbia University, Stanford University, Stanford Linear Accelerator Center (SLAC) (Author)
  • Albert F. Rigosi - , Columbia University, Stanford University, Stanford Linear Accelerator Center (SLAC) (Author)
  • Tony F. Heinz - , Columbia University, Stanford University, Stanford Linear Accelerator Center (SLAC) (Author)

Abstract

Transient changes of the optical response of WS2 monolayers are studied by femtosecond broadband pump-probe spectroscopy. Time-dependent absorption spectra are analyzed by tracking the line width broadening, bleaching, and energy shift of the main exciton resonance as a function of time delay after the excitation. Two main sources for the pump-induced changes of the optical response are identified. Specifically, we find an interplay between modifications induced by many-body interactions from photoexcited carriers and by the subsequent transfer of the excitation to the phonon system followed by cooling of the material through the heat transfer to the substrate.

Details

Original languageEnglish
Pages (from-to)644-651
Number of pages8
JournalNano letters
Volume17
Issue number2
Publication statusPublished - 8 Feb 2017
Peer-reviewedYes
Externally publishedYes

External IDs

PubMed 28059520

Keywords

Keywords

  • Atomically thin 2D materials, carrier and phonon dynamics, ultrafast spectroscopy