The molecular cluster [Bi10Au2](SbBi 3Br9)2
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
(Chemical Equation Presented) A multitude of new binding modes: A [Bi 10Au2]6+ heteroicosahedron and two (SbBi 3Br9)3- hemispheres form molecular cluster [Bi10Au2](SbBi3Br9)2 (see picture: Bi blue, Au yellow, Sb green, Br dark red). The [Bi 10Au2]6+ polycation involves significant bismuth-gold interactions. The molecule also exhibits a rare interpnicogen covalent bond between bismuth and antimony and a complex donor-acceptor bond between the anionic caps and the polycation.
Details
| Original language | English |
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| Pages (from-to) | 3932-3935 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 21 |
| Publication status | Published - 13 May 2008 |
| Peer-reviewed | Yes |
External IDs
| ORCID | /0000-0002-2391-6025/work/166325858 |
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Keywords
ASJC Scopus subject areas
Keywords
- Antimony, Bismuth, Cluster compounds, Gold, Metal-metal interactions