The mixing of Frenkel- and charge-transfer excitons in 1D structures: application to PTCDA and MePTCDI
Research output: Contribution to book/Conference proceedings/Anthology/Report › Chapter in book/Anthology/Report › Contributed › peer-review
Contributors
Abstract
The exciton structure of crystalline PTCDA (3,4,9,10-perylenetetracarboxylic dianhydride) and MePTCDI (N-N'-dimethylperylene-3,4,9, 10-dicarboximide) is modeled by a one-dimensional Hamiltonian, which includes interactions between Frenkel excitons with several vibronic levels and charge transfer excitons. With appropriate fitting parameters, which are verified by quantum chemical calculations, this model can explain the main features of the low temperature absorption spectra. Polarized absorption spectra of MePTCDI show different polarization ratios for the various peaks. This polarization behavior is explained by the varying contribution of the CT transition dipole, which has a direction different from the Frenkel transition dipole.
Details
Original language | German |
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Title of host publication | Multiphoton and Light Driven Multielectron Processes in Organics: New Phenomena, Materials and Applications |
Editors | François Kajzar, M. Vladimir Agranovich |
Place of Publication | Dordrecht |
Publisher | Springer, Dordrecht [u. a.] |
Pages | 123-134 |
Number of pages | 4 |
Volume | 79 |
ISBN (electronic) | 978-94-011-4056-0 |
ISBN (print) | 978-0-7923-6271-5, 978-0-7923-6272-2 |
Publication status | Published - 2000 |
Peer-reviewed | Yes |
Publication series
Series | NATO Science Partnership Subseries: 3 |
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Keywords
Keywords
- Films