The mixing of Frenkel- and charge-transfer excitons in 1D structures: application to PTCDA and MePTCDI

Publikation: Beitrag in Buch/Konferenzbericht/Sammelband/GutachtenBeitrag in Buch/Sammelband/GutachtenBeigetragenBegutachtung

Beitragende

Abstract

The exciton structure of crystalline PTCDA (3,4,9,10-perylenetetracarboxylic dianhydride) and MePTCDI (N-N'-dimethylperylene-3,4,9, 10-dicarboximide) is modeled by a one-dimensional Hamiltonian, which includes interactions between Frenkel excitons with several vibronic levels and charge transfer excitons. With appropriate fitting parameters, which are verified by quantum chemical calculations, this model can explain the main features of the low temperature absorption spectra. Polarized absorption spectra of MePTCDI show different polarization ratios for the various peaks. This polarization behavior is explained by the varying contribution of the CT transition dipole, which has a direction different from the Frenkel transition dipole.

Details

OriginalspracheDeutsch
TitelMultiphoton and Light Driven Multielectron Processes in Organics: New Phenomena, Materials and Applications
Redakteure/-innenFrançois Kajzar, M. Vladimir Agranovich
ErscheinungsortDordrecht
Herausgeber (Verlag)Springer, Dordrecht [u. a.]
Seiten123-134
Seitenumfang4
Band79
ISBN (elektronisch)978-94-011-4056-0
ISBN (Print)978-0-7923-6271-5, 978-0-7923-6272-2
PublikationsstatusVeröffentlicht - 2000
Peer-Review-StatusJa

Publikationsreihe

ReiheNATO Science Partnership Subseries: 3

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  • Films