Synthesis and bonding in platinum(II) complexes with cyclometalated carbene and isoelectronic bis(phosphino)metallocene ligands

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Zdeněk Leitner - , Charles University Prague (Author)
  • Felix Wurl - , Chair of Physical Organic Chemistry, TUD Dresden University of Technology (Author)
  • Jiří Schulz - , Charles University Prague (Author)
  • Ivana Císařová - , Charles University Prague (Author)
  • Thomas Strassner - , Chair of Physical Organic Chemistry, TUD Dresden University of Technology (Author)
  • Petr Štěpnička - , Charles University Prague (Author)

Abstract

Four cycloplatinated complexes of the type [Pt(C^C*){M(η5-C5H4PPh2)2-κ2P,P'}][PF6]n (M = Fe, n = 1; M = Co, n = 2), where C^C* is 2-(3-methylimidazol-2- ylidene-1-yl-κC2)phenyl-κC1 and similar cyclometalated ligands bearing an additional aromatic ring and phenyl substituents at the imidazol-2-ylidene unit, were prepared and structurally characterized by spectroscopic methods (NMR and ESI MS), elemental analysis, cyclic voltammetry and DFT calculations.

Details

Original languageEnglish
Article number123236
JournalJournal of organometallic chemistry
Volume1015
Publication statusPublished - 15 Jul 2024
Peer-reviewedYes

Keywords

ASJC Scopus subject areas

Keywords

  • Carbene complexes, DFT computations, Orthometallated ligands, Phosphine ligands, metallocenes, Platinum complexes, Structure elucidation