Synthesis and bonding in platinum(II) complexes with cyclometalated carbene and isoelectronic bis(phosphino)metallocene ligands
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
Four cycloplatinated complexes of the type [Pt(C^C*){M(η5-C5H4PPh2)2-κ2P,P'}][PF6]n (M = Fe, n = 1; M = Co, n = 2), where C^C* is 2-(3-methylimidazol-2- ylidene-1-yl-κC2)phenyl-κC1 and similar cyclometalated ligands bearing an additional aromatic ring and phenyl substituents at the imidazol-2-ylidene unit, were prepared and structurally characterized by spectroscopic methods (NMR and ESI MS), elemental analysis, cyclic voltammetry and DFT calculations.
Details
| Originalsprache | Englisch |
|---|---|
| Aufsatznummer | 123236 |
| Fachzeitschrift | Journal of organometallic chemistry |
| Jahrgang | 1015 |
| Publikationsstatus | Veröffentlicht - 15 Juli 2024 |
| Peer-Review-Status | Ja |
Schlagworte
ASJC Scopus Sachgebiete
- Biochemie - Carbene complexes, DFT computations, Orthometallated ligands, Phosphine ligands, metallocenes, Platinum complexes, Structure elucidation
- Physikalische und Theoretische Chemie - Carbene complexes, DFT computations, Orthometallated ligands, Phosphine ligands, metallocenes, Platinum complexes, Structure elucidation
- Organische Chemie - Carbene complexes, DFT computations, Orthometallated ligands, Phosphine ligands, metallocenes, Platinum complexes, Structure elucidation
- Anorganische Chemie - Carbene complexes, DFT computations, Orthometallated ligands, Phosphine ligands, metallocenes, Platinum complexes, Structure elucidation
- Werkstoffchemie - Carbene complexes, DFT computations, Orthometallated ligands, Phosphine ligands, metallocenes, Platinum complexes, Structure elucidation
Schlagwörter
- Carbene complexes, DFT computations, Orthometallated ligands, Phosphine ligands, metallocenes, Platinum complexes, Structure elucidation