Swelling and mechanical properties of polymer gels with cross-linking gradient

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Paulo A.L. Fernandes - , Max Planck Institute of Colloids and Interfaces (Author)
  • Stephan Schmidt - , Max Planck Institute of Colloids and Interfaces (Author)
  • Michael Zeiser - , University of Bayreuth (Author)
  • Andreas Fery - , University of Bayreuth (Author)
  • Thomas Hellweg - , University of Bayreuth (Author)

Abstract

We report a novel approach to model the temperature dependence of the volume and elastic modulus of polymer gels with a cross-linking gradient based on the well-known Flory-Rehner (FR) theory. The proposed model consists of dividing the inhomogeneous polymer gel into an arbitrary number of independent and homogeneous layers that are treated independently by the FR approach. Experimental measurements of volume and elastic modulus with atomic force microscopy (AFM) on PNIPAM microgels, unexplained by the classical FR model, are in good agreement with the proposed model.

Details

Original languageEnglish
Pages (from-to)3455-3458
Number of pages4
JournalSoft matter
Volume6
Issue number15
Publication statusPublished - 7 Aug 2010
Peer-reviewedYes
Externally publishedYes

Keywords