Swelling and mechanical properties of polymer gels with cross-linking gradient

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Paulo A.L. Fernandes - , Max Planck Institute of Colloids and Interfaces (Autor:in)
  • Stephan Schmidt - , Max Planck Institute of Colloids and Interfaces (Autor:in)
  • Michael Zeiser - , Universität Bayreuth (Autor:in)
  • Andreas Fery - , Universität Bayreuth (Autor:in)
  • Thomas Hellweg - , Universität Bayreuth (Autor:in)

Abstract

We report a novel approach to model the temperature dependence of the volume and elastic modulus of polymer gels with a cross-linking gradient based on the well-known Flory-Rehner (FR) theory. The proposed model consists of dividing the inhomogeneous polymer gel into an arbitrary number of independent and homogeneous layers that are treated independently by the FR approach. Experimental measurements of volume and elastic modulus with atomic force microscopy (AFM) on PNIPAM microgels, unexplained by the classical FR model, are in good agreement with the proposed model.

Details

OriginalspracheEnglisch
Seiten (von - bis)3455-3458
Seitenumfang4
FachzeitschriftSoft matter
Jahrgang6
Ausgabenummer15
PublikationsstatusVeröffentlicht - 7 Aug. 2010
Peer-Review-StatusJa
Extern publiziertJa