Surface-Synthesized Graphene Nanoribbons for Room Temperature Switching Devices: Substrate Transfer and ex Situ Characterization

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Gabriela Borin Barin - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Andrew Fairbrother - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Lukas Rotach - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Maxime Bayle - , Laboratoire Charles Coulomb (Author)
  • Matthieu Paillet - , Laboratoire Charles Coulomb (Author)
  • Liangbo Liang - , Oak Ridge National Laboratory, Rensselaer Polytechnic Institute (Author)
  • Vincent Meunier - , Rensselaer Polytechnic Institute (Author)
  • Roland Hauert - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Tim Dumslaff - , Max Planck Institute for Polymer Research (Author)
  • Akimitsu Narita - , Max Planck Institute for Polymer Research (Author)
  • Klaus Müllen - , Max Planck Institute for Polymer Research (Author)
  • Hafeesudeen Sahabudeen - , Chair of Molecular Functional Materials (cfaed) (Author)
  • Reinhard Berger - , Chair of Molecular Functional Materials (cfaed) (Author)
  • Xinliang Feng - , Chair of Molecular Functional Materials (cfaed) (Author)
  • Roman Fasel - , University of Bern (Author)
  • Pascal Ruffieux - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)

Abstract

Recent progress in the on-surface synthesis of graphene nanoribbons (GNRs) has given access to atomically precise narrow GNRs with tunable electronic band gaps which makes them excellent candidates for room temperature switching devices such as field-effect transistors (FET). However, in spite of their exceptional properties, significant challenges remain for GNR processing and characterization. This contribution addresses some of the most important challenges, including GNR fabrication scalability, substrate transfer, long-term stability under ambient conditions, and ex situ characterization. We focus on 7- and 9-atom-wide armchair graphene nanoribbons (i.e., 7-AGNR and 9-AGNR) grown on 200 nm Au(111)/mica substrates using a high throughput system. Transfer of both 7- and 9-AGNRs from their Au growth substrate onto various target substrates for additional characterization is accomplished utilizing a polymer-free method that avoids residual contamination. This results in a homogeneous GNR film morphology with very few tears and wrinkles, as examined by atomic force microscopy. Raman spectroscopy indicates no significant degradation of GNR quality upon substrate transfer and reveals that GNRs have remarkable stability under ambient conditions over a 24 month period. The transferred GNRs are analyzed using multiwavelength Raman spectroscopy, which provides detailed insight into the wavelength dependence of the width-specific vibrational modes. Finally, we characterize the optical properties of 7- and 9-AGNRs via ultraviolet-visible (UV-vis) spectroscopy.

Details

Original languageEnglish
Pages (from-to)2184-2192
Number of pages9
JournalACS Applied Nano Materials
Volume2
Issue number4
Publication statusPublished - 26 Apr 2019
Peer-reviewedYes

External IDs

Scopus 85070446997

Keywords

Research priority areas of TU Dresden

Keywords

  • atomic force microscopy, graphene nanoribbons, multiwavelength Raman spectroscopy, optical properties, scanning tunneling microscopy, substrate transfer