Structure and bonding of Pd@[Bi10]4+ in the subbromide Bi14PdBr16

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Michael Ruck - , Chair of Inorganic Chemistry II, TUD Dresden University of Technology (Author)
  • Vitaly Dubenskyy - , TUD Dresden University of Technology (Author)
  • Tilo Söhnel - , TUD Dresden University of Technology (Author)

Abstract

Pd@[Bi10]4+ is the appropriate representation of the first heteronuclear polycation of bismuth and a transition element. The pentagonal Archimedean antiprism [PdBi10]4+ (see picture) is a transition-metal-containing variant of the predicted arachno-cluster [Bi10]4+, in which there are almost no observed host-guest interactions.

Details

Original languageEnglish
Pages (from-to)2978-2982
Number of pages5
JournalAngewandte Chemie - International Edition
Volume42
Issue number26
Publication statusPublished - 7 Jul 2003
Peer-reviewedYes

External IDs

ORCID /0000-0002-2391-6025/work/166325857

Keywords

ASJC Scopus subject areas

Keywords

  • Bismuth, Cluster compounds, Palladium, Polycations, Subvalent compounds