Stereoselective total synthesis of the sesquiterpene (±)-β- isocomene

Research output: Contribution to journal › Letter › Contributed › peer-review

Contributors

  • Arndt W. Schmidt - , Chair of Organic Chemistry II (Author)
  • Thomas Olpp - , TUD Dresden University of Technology (Author)
  • Elke Baum - , TUD Dresden University of Technology (Author)
  • Tina Stiffel - , TUD Dresden University of Technology (Author)
  • Hans Joachim Knölker - , Chair of Organic Chemistry II (Author)

Abstract

Application of the Lewis acid mediated [3+2] cycloaddition of allyl-tert-butyldiphenylsilane combined with a modified Fleming-Tamao oxidation provides a stereoselective route to the triquinane sesquiterpene (±)-β-isocomene.

Details

Original languageEnglish
Pages (from-to)2371-2374
Number of pages4
JournalSynlett
Volume2007
Issue number15
Publication statusPublished - 17 Sept 2007
Peer-reviewedYes

Keywords

ASJC Scopus subject areas

Keywords

  • Cycloadditions, Lewis acids, Silicon, Stereoselective synthesis, Terpenoids