Splitting of Surface-Immobilized Multicompartment Micelles into Clusters upon Charge Inversion

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Inna Dewald - , University of Bayreuth (Author)
  • Julia Gensel - , University of Bayreuth (Author)
  • Eva Betthausen - , University of Bayreuth (Author)
  • Oleg V. Borisov - , Université de Pau et des Pays de l'Adour, Peter the Great St. Petersburg Polytechnic University (Author)
  • Axel H.E. Müller - , University of Bayreuth, Johannes Gutenberg University Mainz (Author)
  • Felix H. Schacher - , Friedrich Schiller University Jena (Author)
  • Andreas Fery - , Center for Advancing Electronics Dresden (cfaed), University of Bayreuth, Leibniz Institute of Polymer Research Dresden (Author)

Abstract

We investigate a morphological transition of surface-immobilized triblock terpolymer micelles: the splitting into well-defined clusters of satellite micelles upon pH changes. The multicompartment micelles are formed in aqueous solution of ABC triblock terpolymers consisting of a hydrophobic polybutadiene block, a weak polyanionic poly(methacrylic acid) block, and a weak polycationic poly(2-(dimethylamino)ethyl methacrylate) block. They are subsequently immobilized on silicon wafer surfaces by dip-coating. The splitting process is triggered by a pH change to strongly basic pH, which goes along with a charge reversal of the micelles. We find that the aggregation number of the submicelles is well-defined and that larger micelles have a tendency to split into a larger number of submicelles. Furthermore, there is a clear preference for clusters consisting of doublets and triplets of submicelles. The morphology of surface-immobilized clusters can be "quenched" by returning to the original pH. Thus, such well-defined micellar clusters can be stabilized and are available as colloidal building blocks for the formation of hierarchical surface structures. We discuss the underlying physicochemical principles of the splitting process considering changes in charge and total free energy of the micelles upon pH change.

Details

Original languageEnglish
Pages (from-to)5180-5188
Number of pages9
JournalACS nano
Volume10
Issue number5
Publication statusPublished - 24 May 2016
Peer-reviewedYes

Keywords

Keywords

  • ABC triblock terpolymer, atomic force microscopy, cluster formation, micelle splitting, multicompartment micelles, smart coatings, surface immobilization