Spectral Properties of Molecular Oligomers: A Non-Markovian Quantum State Diffusion Approach
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Contributors
Abstract
Absorption spectra of small molecular aggregates (oligomers) are considered. The dipole-dipole interaction between the monomers leads to shifts of the oligomer spectra with respect to the monomer absorption. The line-shapes of monomer as well as oligomer absorption depend strongly on the coupling to vibrational modes. Using a recently developed approach [Roden et al., PRL 103, 058301] we investigate the length dependence of spectra of one-dimensional aggregates for various values of the interaction strength between the monomers. It is demonstrated, that the present approach is well suited to describe the occurrence of the J- and H-bands.
Details
Original language | English |
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Pages (from-to) | 5060-5067 |
Number of pages | 8 |
Journal | International Journal of Modern Physics B |
Volume | 2010 |
Issue number | 24, No. 25n26 |
Publication status | Published - 2010 |
Peer-reviewed | Yes |
External IDs
Scopus | 79551576772 |
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ORCID | /0000-0002-7806-3525/work/142234204 |
Keywords
Keywords
- molecular aggregates, non-markovian quantum state diffusion, absorption spectra