Spectral Properties of Molecular Oligomers: A Non-Markovian Quantum State Diffusion Approach

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Absorption spectra of small molecular aggregates (oligomers) are considered. The dipole-dipole interaction between the monomers leads to shifts of the oligomer spectra with respect to the monomer absorption. The line-shapes of monomer as well as oligomer absorption depend strongly on the coupling to vibrational modes. Using a recently developed approach [Roden et al., PRL 103, 058301] we investigate the length dependence of spectra of one-dimensional aggregates for various values of the interaction strength between the monomers. It is demonstrated, that the present approach is well suited to describe the occurrence of the J- and H-bands.

Details

Original languageEnglish
Pages (from-to)5060-5067
Number of pages8
JournalInternational Journal of Modern Physics B
Volume2010
Issue number24, No. 25n26
Publication statusPublished - 2010
Peer-reviewedYes

External IDs

Scopus 79551576772
ORCID /0000-0002-7806-3525/work/142234204

Keywords

Keywords

  • molecular aggregates, non-markovian quantum state diffusion, absorption spectra