Spectral Properties of Molecular Oligomers: A Non-Markovian Quantum State Diffusion Approach

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

Absorption spectra of small molecular aggregates (oligomers) are considered. The dipole-dipole interaction between the monomers leads to shifts of the oligomer spectra with respect to the monomer absorption. The line-shapes of monomer as well as oligomer absorption depend strongly on the coupling to vibrational modes. Using a recently developed approach [Roden et al., PRL 103, 058301] we investigate the length dependence of spectra of one-dimensional aggregates for various values of the interaction strength between the monomers. It is demonstrated, that the present approach is well suited to describe the occurrence of the J- and H-bands.

Details

OriginalspracheEnglisch
Seiten (von - bis)5060-5067
Seitenumfang8
FachzeitschriftInternational Journal of Modern Physics B
Jahrgang2010
Ausgabenummer24, No. 25n26
PublikationsstatusVeröffentlicht - 2010
Peer-Review-StatusJa

Externe IDs

Scopus 79551576772
ORCID /0000-0002-7806-3525/work/142234204

Schlagworte

Schlagwörter

  • molecular aggregates, non-markovian quantum state diffusion, absorption spectra