Solid-state NMR insights into alcohol adsorption by metal–organic frameworks: adsorption state, selectivity, and adsorption-induced phase transitions

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Alcohol adsorption by metal-organic frameworks (ZIF-8 and ZIF-11) in aqueous solutions is investigated including alcohol mixtures. Solid-state 13C NMR spectroscopy is demonstrated to be well-suited for such liquid-phase adsorption studies at the molecular level. Adsorption-induced immobilization could be visualized. Finally, an unexpected phase transition of ZIF-11 was discovered.

Details

Original languageEnglish
Pages (from-to)4492-4495
Number of pages4
JournalChemical communications
Volume58
Issue number28
Publication statusPublished - 2022
Peer-reviewedYes

External IDs

Scopus 85127553359
Mendeley 0e5664f4-e4a4-3565-a14a-b38b9f627b81
WOS 000770344800001
unpaywall 10.1039/d2cc00638c

Keywords