Solid-state NMR insights into alcohol adsorption by metal–organic frameworks: adsorption state, selectivity, and adsorption-induced phase transitions

Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung

Beitragende

Abstract

Alcohol adsorption by metal-organic frameworks (ZIF-8 and ZIF-11) in aqueous solutions is investigated including alcohol mixtures. Solid-state 13C NMR spectroscopy is demonstrated to be well-suited for such liquid-phase adsorption studies at the molecular level. Adsorption-induced immobilization could be visualized. Finally, an unexpected phase transition of ZIF-11 was discovered.

Details

OriginalspracheEnglisch
Seiten (von - bis)4492-4495
Seitenumfang4
FachzeitschriftChemical communications
Jahrgang58
Ausgabenummer28
PublikationsstatusVeröffentlicht - 2022
Peer-Review-StatusJa

Externe IDs

Scopus 85127553359
Mendeley 0e5664f4-e4a4-3565-a14a-b38b9f627b81
WOS 000770344800001
unpaywall 10.1039/d2cc00638c

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