Robust Magneto-Ionic Effect in Fe/FeOx Thin Films in Electrolytes With Different Cations

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • J. Zehner - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • O. Vaerst - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • I. Soldatov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • K. Nielsch - , Chair of Metallic Materials and Metal Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • R. Schafer - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • K. Leistner - , Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

Electrochemical reactions offer an elegant way to influence the magnetic properties of nanoscaled materials by applying a small voltage. The present study focuses on such magneto-ionic changes in thin Fe/FeOx films induced by interfacial electrochemical reactions in liquid electrolytes. The films are prepared by inclined sputter deposition and exhibit a uniaxial in-plane anisotropy. LiOH, NaOH, and KOH in an aqueous solution are used as electrolytes. The changes in the hysteresis loops and the magnetic microstructure are observed by in-situ Kerr microscopy. Upon low voltage application, the electrochemical reduction reaction leads to the transformation of the FeOx-layer into the metallic Fe. Simultaneously, a strong decrease of coercivity and remanence together with an increase of domain size occurs. These observations are in line with a previously reported magnetic de-blocking mechanism caused by the variation of Néel wall interactions during the oxide-metal transformation. When applying the oxidation potential, the coercivity, remanence, and domain size are re-established. The changes occur in a similar manner for all studied electrolytes and can be repeatedly achieved for multiple voltage switching steps. This evidences that the electrochemical reaction mechanism responsible for the magneto-ionic switching is very robust and dictated by the anion (OH-) rather than the type of cation.

Details

Original languageEnglish
JournalIEEE transactions on magnetics
Volume58
Issue number2
Publication statusPublished - 1 Feb 2022
Peer-reviewedYes

Keywords

Keywords

  • Functional materials, magneto-electric, voltage control of magnetic anisotropy, voltage control of magnetic domains