Probing Interlayer Interactions in Transition Metal Dichalcogenide Heterostructures by Optical Spectroscopy: MoS2/WS2 and MoSe2/WSe2
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
We have applied optical absorption spectroscopy to investigate van der Waals heterostructures formed of pairs of monolayer transition metal dichalcogenide crystals, choosing MoS2/WS2 and MoSe2/WSe2 as test cases. In the heterostructure spectra, we observe a significant broadening of the excitonic transitions compared to the corresponding features in the isolated layers. The broadening is interpreted as a lifetime effect arising from decay of excitons initially created in either layer through charge transfer processes expected for a staggered band alignment. The measured spectral broadening of 20 meV-35 meV implies lifetimes for charge separation of the near band-edge A and B excitons in the range of 20-35 fs. Higher-lying transitions exhibit still greater broadening.
Details
| Original language | English |
|---|---|
| Pages (from-to) | 5033-5038 |
| Number of pages | 6 |
| Journal | Nano letters |
| Volume | 15 |
| Issue number | 8 |
| Publication status | Published - 12 Aug 2015 |
| Peer-reviewed | Yes |
| Externally published | Yes |
External IDs
| PubMed | 26186085 |
|---|---|
| ORCID | /0000-0002-9213-2777/work/196666217 |
Keywords
ASJC Scopus subject areas
Keywords
- 2D materials, charge transfer, heterostructures, lifetime broadening, transition metal dichalcogenides