Probing Interlayer Interactions in Transition Metal Dichalcogenide Heterostructures by Optical Spectroscopy: MoS2/WS2 and MoSe2/WSe2

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Albert F. Rigosi - , Columbia University (Author)
  • Heather M. Hill - , Columbia University (Author)
  • Yilei Li - , Columbia University (Author)
  • Alexey Chernikov - , Columbia University (Author)
  • Tony F. Heinz - , Columbia University (Author)

Abstract

We have applied optical absorption spectroscopy to investigate van der Waals heterostructures formed of pairs of monolayer transition metal dichalcogenide crystals, choosing MoS2/WS2 and MoSe2/WSe2 as test cases. In the heterostructure spectra, we observe a significant broadening of the excitonic transitions compared to the corresponding features in the isolated layers. The broadening is interpreted as a lifetime effect arising from decay of excitons initially created in either layer through charge transfer processes expected for a staggered band alignment. The measured spectral broadening of 20 meV-35 meV implies lifetimes for charge separation of the near band-edge A and B excitons in the range of 20-35 fs. Higher-lying transitions exhibit still greater broadening.

Details

Original languageEnglish
Pages (from-to)5033-5038
Number of pages6
JournalNano letters
Volume15
Issue number8
Publication statusPublished - 12 Aug 2015
Peer-reviewedYes
Externally publishedYes

External IDs

PubMed 26186085

Keywords

Keywords

  • 2D materials, charge transfer, heterostructures, lifetime broadening, transition metal dichalcogenides