Probing Interlayer Interactions in Transition Metal Dichalcogenide Heterostructures by Optical Spectroscopy: MoS2/WS2 and MoSe2/WSe2
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
We have applied optical absorption spectroscopy to investigate van der Waals heterostructures formed of pairs of monolayer transition metal dichalcogenide crystals, choosing MoS2/WS2 and MoSe2/WSe2 as test cases. In the heterostructure spectra, we observe a significant broadening of the excitonic transitions compared to the corresponding features in the isolated layers. The broadening is interpreted as a lifetime effect arising from decay of excitons initially created in either layer through charge transfer processes expected for a staggered band alignment. The measured spectral broadening of 20 meV-35 meV implies lifetimes for charge separation of the near band-edge A and B excitons in the range of 20-35 fs. Higher-lying transitions exhibit still greater broadening.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 5033-5038 |
Seitenumfang | 6 |
Fachzeitschrift | Nano letters |
Jahrgang | 15 |
Ausgabenummer | 8 |
Publikationsstatus | Veröffentlicht - 12 Aug. 2015 |
Peer-Review-Status | Ja |
Extern publiziert | Ja |
Externe IDs
PubMed | 26186085 |
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Schlagworte
ASJC Scopus Sachgebiete
Schlagwörter
- 2D materials, charge transfer, heterostructures, lifetime broadening, transition metal dichalcogenides