Polystyrene with different topologies: Study of the glass transition temperature in confined geometry of thin films
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
The glass transition behaviour of polystyrene (PS) with systematically varied topologies (linear, star-like and hyperbranched) confined in nanoscalic films was studied by means of spectroscopic vis-ellipsometry. All applied PS samples showed no or only a marginal depression in glass transition temperature T(g) in the order hyperbranched PS (5 K)> starlike PS (3 K) > linear PS (0 K) for the thinnest films analyzed. The T(g) behaviour was accompanied by the observation of the film density in dependence of film thickness. A maximum decreased density of about 7% for hyperbranched PS and 5% for star-like PS and again no deviation in density of bulk was found for linear PS. Accordingly, we deduce from these results considering an experimental accuracy of about +/- 2 K for T(g) and up to +/- 3% for film density, that the polymer topology only barely influences T(g) in the confinement of thin films. (C) 2010 Elsevier Ltd. All rights reserved.
Details
| Original language | English |
|---|---|
| Pages (from-to) | 2240-2246 |
| Number of pages | 7 |
| Journal | European Polymer Journal |
| Volume | 46 |
| Issue number | 12 |
| Publication status | Published - Dec 2010 |
| Peer-reviewed | Yes |
| Externally published | Yes |
External IDs
| Scopus | 83655185853 |
|---|---|
| ORCID | /0000-0002-4531-691X/work/148607823 |
Keywords
Keywords
- Confinement effects, Glass transition, Polymer, Thin films, Topology