Polystyrene with different topologies: Study of the glass transition temperature in confined geometry of thin films

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • M. Erber - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • K-J. Eichhorn - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • B. Voit - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)

Abstract

The glass transition behaviour of polystyrene (PS) with systematically varied topologies (linear, star-like and hyperbranched) confined in nanoscalic films was studied by means of spectroscopic vis-ellipsometry. All applied PS samples showed no or only a marginal depression in glass transition temperature T(g) in the order hyperbranched PS (5 K)> starlike PS (3 K) > linear PS (0 K) for the thinnest films analyzed. The T(g) behaviour was accompanied by the observation of the film density in dependence of film thickness. A maximum decreased density of about 7% for hyperbranched PS and 5% for star-like PS and again no deviation in density of bulk was found for linear PS. Accordingly, we deduce from these results considering an experimental accuracy of about +/- 2 K for T(g) and up to +/- 3% for film density, that the polymer topology only barely influences T(g) in the confinement of thin films. (C) 2010 Elsevier Ltd. All rights reserved.

Details

OriginalspracheEnglisch
Seiten (von - bis)2240-2246
Seitenumfang7
FachzeitschriftEuropean Polymer Journal
Jahrgang46
Ausgabenummer12
PublikationsstatusVeröffentlicht - Dez. 2010
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

Scopus 83655185853
ORCID /0000-0002-4531-691X/work/148607823

Schlagworte

Schlagwörter

  • Confinement effects, Glass transition, Polymer, Thin films, Topology