Polystyrene with different topologies: Study of the glass transition temperature in confined geometry of thin films
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
The glass transition behaviour of polystyrene (PS) with systematically varied topologies (linear, star-like and hyperbranched) confined in nanoscalic films was studied by means of spectroscopic vis-ellipsometry. All applied PS samples showed no or only a marginal depression in glass transition temperature T(g) in the order hyperbranched PS (5 K)> starlike PS (3 K) > linear PS (0 K) for the thinnest films analyzed. The T(g) behaviour was accompanied by the observation of the film density in dependence of film thickness. A maximum decreased density of about 7% for hyperbranched PS and 5% for star-like PS and again no deviation in density of bulk was found for linear PS. Accordingly, we deduce from these results considering an experimental accuracy of about +/- 2 K for T(g) and up to +/- 3% for film density, that the polymer topology only barely influences T(g) in the confinement of thin films. (C) 2010 Elsevier Ltd. All rights reserved.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 2240-2246 |
Seitenumfang | 7 |
Fachzeitschrift | European Polymer Journal |
Jahrgang | 46 |
Ausgabenummer | 12 |
Publikationsstatus | Veröffentlicht - Dez. 2010 |
Peer-Review-Status | Ja |
Extern publiziert | Ja |
Externe IDs
Scopus | 83655185853 |
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ORCID | /0000-0002-4531-691X/work/148607823 |
Schlagworte
Schlagwörter
- Confinement effects, Glass transition, Polymer, Thin films, Topology