Phase equilibria of carbon dioxide and methane gas-hydrates predicted with the modified analytical S-L-V equation of state
Research output: Contribution to journal › Conference article › Contributed › peer-review
Contributors
Abstract
Gas-hydrates (clathrates) are non-stoichiometric crystallized solutions of gas molecules in the metastable water lattice. Two or more components are associated without ordinary chemical union but through complete enclosure of gas molecules in a framework of water molecules linked together by hydrogen bonds. The clathrates are important in the following applications: the pipeline blockage in natural gas industry, potential energy source in the form of natural hydrates present in ocean bottom, and the CO2 separation and storage. In this study, we have modified an analytical solid-liquid-vapor equation of state (EoS) [A. Yokozeki, Fluid Phase Equil. 222-223 (2004)] to improve its ability for modeling the phase equilibria of clathrates. The EoS can predict the formation conditions for CO2-and CH4- hydrates. It will be used as an initial estimate for a more complicated hydrate model based on the fundamental EoSs for fluid phases.
Details
Original language | English |
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Article number | 01098 |
Journal | EPJ Web of Conferences |
Volume | 25 |
Publication status | Published - 2012 |
Peer-reviewed | Yes |
Externally published | Yes |
Conference
Title | Conference on Experimental Fluid Mechanics, EFM 2011 |
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Duration | 22 - 25 November 2011 |
City | Jicin |
Country | Czech Republic |
External IDs
ORCID | /0000-0001-7908-4160/work/168204397 |
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