Phase equilibria of carbon dioxide and methane gas-hydrates predicted with the modified analytical S-L-V equation of state

Publikation: Beitrag in FachzeitschriftKonferenzartikelBeigetragenBegutachtung

Beitragende

  • Václav Vinš - , Czech Academy of Sciences (Autor:in)
  • Andreas Jäger - , Ruhr-Universität Bochum (Autor:in)
  • Jan Hrubý - , Czech Academy of Sciences (Autor:in)
  • Roland Span - , Ruhr-Universität Bochum (Autor:in)

Abstract

Gas-hydrates (clathrates) are non-stoichiometric crystallized solutions of gas molecules in the metastable water lattice. Two or more components are associated without ordinary chemical union but through complete enclosure of gas molecules in a framework of water molecules linked together by hydrogen bonds. The clathrates are important in the following applications: the pipeline blockage in natural gas industry, potential energy source in the form of natural hydrates present in ocean bottom, and the CO2 separation and storage. In this study, we have modified an analytical solid-liquid-vapor equation of state (EoS) [A. Yokozeki, Fluid Phase Equil. 222-223 (2004)] to improve its ability for modeling the phase equilibria of clathrates. The EoS can predict the formation conditions for CO2-and CH4- hydrates. It will be used as an initial estimate for a more complicated hydrate model based on the fundamental EoSs for fluid phases.

Details

OriginalspracheEnglisch
Aufsatznummer01098
FachzeitschriftEPJ Web of Conferences
Jahrgang25
PublikationsstatusVeröffentlicht - 2012
Peer-Review-StatusJa
Extern publiziertJa

Konferenz

TitelConference on Experimental Fluid Mechanics, EFM 2011
Dauer22 - 25 November 2011
StadtJicin
LandTschechische Republik

Externe IDs

ORCID /0000-0001-7908-4160/work/168204397

Schlagworte

ASJC Scopus Sachgebiete