[P3Se4]+: A Binary Phosphorus-Selenium Cation
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Although a fairly large number of binary group 15/16 element cations have been reported, no example involving phosphorus in combination with a group 16 element has been synthesized and characterized to date. In this contribution is reported the synthesis and structural characterization of the first example of such a cation, namely a nortricyclane-type [P3Se4]+. This cation has been independently discovered by three groups through three different synthetic routes, as described herein. The molecular and electronic structure of the [P3Se4]+ cage and its crystal properties in the solid state have been characterized comprehensively by using X-ray diffraction, Raman, and nuclear magnetic resonance spectroscopies, as well as quantum chemical calculations.
Details
Original language | English |
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Pages (from-to) | 9697-9712 |
Number of pages | 16 |
Journal | Chemistry - A European Journal |
Volume | 21 |
Issue number | 27 |
Publication status | Published - 1 Jun 2015 |
Peer-reviewed | Yes |
External IDs
ORCID | /0000-0002-2391-6025/work/159171872 |
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ORCID | /0000-0001-7323-7816/work/159172466 |
Scopus | 84935038026 |
Keywords
Keywords
- cations, main group elements, NMR spectroscopy, quantum chemistry, structure elucidation