Negative plasmon dispersion in 2H-NbS2beyond the charge-density-wave interpretation

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Pierluigi Cudazzo - , Université Paris-Saclay, Nano-Bio Spectroscopy Group and European Theoretical Spectroscopy Facility (ETSF) (First author)
  • Eric Müller - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Carsten Habenicht - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Matteo Gatti - , Université Paris-Saclay, Nano-Bio Spectroscopy Group and European Theoretical Spectroscopy Facility (ETSF), French Alternative Energies and Atomic Energy Commission (CEA) (Author)
  • Helmuth Berger - , Swiss Federal Institute of Technology Lausanne (EPFL) (Author)
  • Martin Knupfer - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Angel Rubio - , Max Planck Institute for the Structure and Dynamics of Matter, Nano-Bio Spectroscopy Group and European Theoretical Spectroscopy Facility (ETSF) (Author)
  • Simo Huotari - , University of Helsinki (Last author)

Abstract

We examine the experimental and theoretical electron-energy loss spectra in 2H-Cu0.2NbS2 and find that the 1 eV plasmon in this material does not exhibit the regular positive quadratic plasmon dispersion that would be expected for a normal broad-parabolic-band system. Instead we find a nearly non-dispersing plasmon in the momentum-transfer range q < 0.35 Å−1 . We argue that for a stoichiometric pure 2H-NbS2 the dispersion relation is expected to have a negative slope as is the case for other transition-metal dichalcogenides. The presence of Cu impurities, required to stabilize the crystal growth, tends to shift the negative plasmon dispersion into a positive one, but the doping level in the current system is small enough to result in a nearly-non-dispersing plasmon. We conclude that a negative-slope plasmon dispersion is not connected with the existence of a charge-density-wave order in transition metal dichalcogenides.

Details

Original languageEnglish
Pages (from-to)103050
Number of pages7
JournalNew journal of physics
Volume18
Publication statusPublished - 26 Oct 2016
Peer-reviewedYes
Externally publishedYes

External IDs

Scopus 84992691690

Keywords