Negative plasmon dispersion in 2H-NbS2beyond the charge-density-wave interpretation
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
We examine the experimental and theoretical electron-energy loss spectra in 2H-${\mathrm{Cu}}_{0.2}$NbS2 and find that the 1 eV plasmon in this material does not exhibit the regular positive quadratic plasmon dispersion that would be expected for a normal broad-parabolic-band system. Instead we find a nearly non-dispersing plasmon in the momentum-transfer range $q\lt 0.35$ Å−1. We argue that for a stoichiometric pure 2H-NbS2 the dispersion relation is expected to have a negative slope as is the case for other transition-metal dichalcogenides. The presence of Cu impurities, required to stabilize the crystal growth, tends to shift the negative plasmon dispersion into a positive one, but the doping level in the current system is small enough to result in a nearly-non-dispersing plasmon. We conclude that a negative-slope plasmon dispersion is not connected with the existence of a charge-density-wave order in transition metal dichalcogenides.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 103050 |
Seitenumfang | 7 |
Fachzeitschrift | New journal of physics |
Jahrgang | 18 |
Publikationsstatus | Veröffentlicht - 26 Okt. 2016 |
Peer-Review-Status | Ja |
Extern publiziert | Ja |
Externe IDs
Scopus | 84992691690 |
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