Negative plasmon dispersion in 2H-NbS2beyond the charge-density-wave interpretation

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Pierluigi Cudazzo - , Université Paris-Saclay, Nano-Bio Spectroscopy Group and European Theoretical Spectroscopy Facility (ETSF) (Erstautor:in)
  • Eric Müller - , Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (Autor:in)
  • Carsten Habenicht - , Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (Autor:in)
  • Matteo Gatti - , Université Paris-Saclay, Nano-Bio Spectroscopy Group and European Theoretical Spectroscopy Facility (ETSF), Commissariat à l’énergie atomique et aux énergies alternatives (CEA) (Autor:in)
  • Helmuth Berger - , École Polytechnique Fédérale de Lausanne (Autor:in)
  • Martin Knupfer - , Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (Autor:in)
  • Angel Rubio - , Max Planck Institute for the Structure and Dynamics of Matter, Nano-Bio Spectroscopy Group and European Theoretical Spectroscopy Facility (ETSF) (Autor:in)
  • Simo Huotari - , University of Helsinki (Letztautor:in)

Abstract

We examine the experimental and theoretical electron-energy loss spectra in 2H-${\mathrm{Cu}}_{0.2}$NbS2 and find that the 1 eV plasmon in this material does not exhibit the regular positive quadratic plasmon dispersion that would be expected for a normal broad-parabolic-band system. Instead we find a nearly non-dispersing plasmon in the momentum-transfer range $q\lt 0.35$ Å−1. We argue that for a stoichiometric pure 2H-NbS2 the dispersion relation is expected to have a negative slope as is the case for other transition-metal dichalcogenides. The presence of Cu impurities, required to stabilize the crystal growth, tends to shift the negative plasmon dispersion into a positive one, but the doping level in the current system is small enough to result in a nearly-non-dispersing plasmon. We conclude that a negative-slope plasmon dispersion is not connected with the existence of a charge-density-wave order in transition metal dichalcogenides.

Details

OriginalspracheEnglisch
Seiten (von - bis)103050
Seitenumfang7
FachzeitschriftNew journal of physics
Jahrgang18
PublikationsstatusVeröffentlicht - 26 Okt. 2016
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

Scopus 84992691690

Schlagworte