Near surface inversion layer recombination in Al2O3 passivated n -type silicon

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Ingo Dirnstorfer - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Daniel K. Simon - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Paul M. Jordan - , NaMLab - Nanoelectronic materials laboratory gGmbH (Author)
  • Thomas Mikolajick - , Institute of Semiconductors and Microsystems, NaMLab - Nanoelectronic materials laboratory gGmbH (Author)

Abstract

On n-type silicon, negatively charged surface passivation layers create a near surface recombination channel, which could significantly reduce the effective carrier lifetime at low injection levels (Δn < 10 14cm-3). This effect is described by Shockley Read Hall recombination at homogeneously distributed defects in the silicon wafer. In the near surface region, fixed charges in the dielectric layer significantly change the carrier concentrations and the recombination rate of defects. Sentaurus device simulations show that the contribution of the near surface recombination to the effective carrier lifetime depends on the properties of the involved defects. The lifetime reduction is strongest when the involved defects have an energy level in the lower half of the band gap and a very high electron to hole capture cross section ratio. For the simulation, a very low defect density in the order of 108cm-3 is assumed, which is a realistic value in highly pure float zone silicon. Quasi-steady state photoconductance measurements on n-type silicon with Al2O3 passivation are done and fitted with the recombination model. Very good correlation between simulation and experiment is achieved when the involved recombination centers have an electron to hole capture cross section ratio of 107 and an energy level of -0.2 eV w.r.t. the intrinsic level. The simulated defect properties are discussed in respect of transition metal and doping related defects reported in literature.

Details

Original languageEnglish
Article number044112
JournalJournal of applied physics
Volume116
Issue number4
Publication statusPublished - 28 Jul 2014
Peer-reviewedYes

External IDs

ORCID /0000-0003-3814-0378/work/142256297

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