Nanoscale domain engineering and characterization of ferroelectric domains

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Nanoscale domain engineering in ferroelectric crystals is demonstrated down to a lateral domain size of 25 nm in diameter using scanning force microscopy (SFM). The various modes of SFM are used to measure both the internal polarization field and external stray field arising from bound surface charges in ferroelectric domains. From these measurements the effective three-dimensional arrangement of ferroelectric domains is reconstructed. Domain switching is initiated applying strong electric fields between the tip and counter electrode. The size of freshly nucleated domains is found to depend dramatically on the switching conditions, i.e. the applied electric field strength and switching time. Domains of less than 100 nm in diameter result for an electric field Eexp>50 kV cm-1 applied for an ultra-short time period τexp<30 μs. Also, the coercive field of nanoscale ferroelectric domains in BaTiO3 single crystals is found to measure 1.4 kV cm-1, much more than the bulk value. Analysis of the transient response during domain switching shows that domain nucleation proceeds within less than 100 μs. With these tools we are able to record nanoscale hysteresis loops monitoring both the successful domain reversal and a well established material contrast between different ferroelectric structures with a resolution of better than 0.1%.

Details

Original languageEnglish
Pages (from-to)405-411
Number of pages7
JournalNanotechnology
Volume10
Issue number4
Publication statusPublished - Dec 1999
Peer-reviewedYes

External IDs

ORCID /0000-0002-2484-4158/work/158768118