Nanorattles with tailored electric field enhancement

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Max J. Schnepf - , Leibniz Institute of Polymer Research Dresden (Author)
  • Martin Mayer - , Center for Advancing Electronics Dresden (cfaed), Leibniz Institute of Polymer Research Dresden (Author)
  • Christian Kuttner - , Leibniz Institute of Polymer Research Dresden, TUD Dresden University of Technology (Author)
  • Moritz Tebbe - , University of Bayreuth, University of Toronto (Author)
  • Daniel Wolf - , Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • Martin Dulle - , University of Bayreuth (Author)
  • Thomas Altantzis - , University of Antwerp (Author)
  • Petr Formanek - , Leibniz Institute of Polymer Research Dresden (Author)
  • Stephan Förster - , University of Bayreuth (Author)
  • Sara Bals - , University of Antwerp (Author)
  • Tobias A.F. König - , Leibniz Institute of Polymer Research Dresden, TUD Dresden University of Technology (Author)
  • Andreas Fery - , Chair of Physical Chemistry of Polymeric Materials, Center for Advancing Electronics Dresden (cfaed), Leibniz Institute of Polymer Research Dresden (Author)

Abstract

Nanorattles are metallic core-shell particles with core and shell separated by a dielectric spacer. These nanorattles have been identified as a promising class of nanoparticles, due to their extraordinary high electric-field enhancement inside the cavity. Limiting factors are reproducibility and loss of axial symmetry owing to the movable metal core; movement of the core results in fluctuation of the nanocavity dimensions and commensurate variations in enhancement factor. We present a novel synthetic approach for the robust fixation of the central gold rod within a well-defined box, which results in an axisymmetric nanorattle. We determine the structure of the resulting axisymmetric nanorattles by advanced transmission electron microscopy (TEM) and small-angle X-ray scattering (SAXS). Optical absorption and scattering cross-sections obtained from UV-vis-NIR spectroscopy quantitatively agree with finite-difference time-domain (FDTD) simulations based on the structural model derived from SAXS. The predictions of high and homogenous field enhancement are evidenced by scanning TEM electron energy loss spectroscopy (STEM-EELS) measurement on single-particle level. Thus, comprehensive understanding of structural and optical properties is achieved for this class of nanoparticles, paving the way for photonic applications where a defined and robust unit cell is crucial.

Details

Original languageEnglish
Pages (from-to)9376-9385
Number of pages10
JournalNanoscale
Volume9
Issue number27
Publication statusPublished - 21 Jul 2017
Peer-reviewedYes

External IDs

PubMed 28656183