Monovacancy paramagnetism in neutron-irradiated graphite probed by 13C NMR

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Z. T. Zhang - , Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • C. Xu - , Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • D. Dmytriieva - , Helmholtz-Zentrum Dresden-Rossendorf, TUD Dresden University of Technology (Author)
  • S. Molatta - , Chair of Physics of High Magnetic Fields, Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • J. Wosnitza - , Chair of Physics of High Magnetic Fields, Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • Y. T. Wang - , Helmholtz-Zentrum Dresden-Rossendorf, Xidian University (Author)
  • M. Helm - , Chair of Semiconductor Spectroscopy, Helmholtz-Zentrum Dresden-Rossendorf, TUD Dresden University of Technology (Author)
  • Shengqiang Zhou - , Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • H. Kühne - , Helmholtz-Zentrum Dresden-Rossendorf (Author)

Abstract

We report on the magnetic properties of monovacancy defects in neutron-irradiated graphite, probed by 13C nuclear magnetic resonance spectroscopy. The bulk paramagnetism of the defect moments is revealed by the temperature dependence of the NMR frequency shift and spectral linewidth, both of which follow a Curie behavior, in agreement with measurements of the macroscopic magnetization. Compared to pristine graphite, the fluctuating hyperfine fields generated by the defect moments lead to an enhancement of the 13C nuclear spin-lattice relaxation rate 1/T1 by about two orders of magnitude. With an applied magnetic field of 7.1 T, the temperature dependence of 1/T1 below about 10 K can well be described by a thermally activated form, 1/T1α exp(-/KBT) , yielding a singular Zeeman energy of () meV, in excellent agreement with the sole presence of polarized, non-interacting defect moments.

Details

Original languageEnglish
Article number465801
JournalJournal of Physics Condensed Matter
Volume29
Issue number46
Publication statusPublished - 19 Oct 2017
Peer-reviewedYes

External IDs

PubMed 29053468

Keywords

Keywords

  • defect magnetism, graphite, nuclear magnetic resonance