Monovacancy paramagnetism in neutron-irradiated graphite probed by 13C NMR

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

We report on the magnetic properties of monovacancy defects in neutron-irradiated graphite, probed by 13C nuclear magnetic resonance spectroscopy. The bulk paramagnetism of the defect moments is revealed by the temperature dependence of the NMR frequency shift and spectral linewidth, both of which follow a Curie behavior, in agreement with measurements of the macroscopic magnetization. Compared to pristine graphite, the fluctuating hyperfine fields generated by the defect moments lead to an enhancement of the 13C nuclear spin-lattice relaxation rate 1/T1 by about two orders of magnitude. With an applied magnetic field of 7.1 T, the temperature dependence of 1/T1 below about 10 K can well be described by a thermally activated form, 1/T1α exp(-/KBT) , yielding a singular Zeeman energy of () meV, in excellent agreement with the sole presence of polarized, non-interacting defect moments.

Details

OriginalspracheEnglisch
Aufsatznummer465801
FachzeitschriftJournal of Physics Condensed Matter
Jahrgang29
Ausgabenummer46
PublikationsstatusVeröffentlicht - 19 Okt. 2017
Peer-Review-StatusJa

Externe IDs

PubMed 29053468

Schlagworte

Schlagwörter

  • defect magnetism, graphite, nuclear magnetic resonance