LaTe1.9: a tenfold superstructure of the ZrSSi type

Research output: Contribution to journalResearch articleContributedpeer-review

Abstract

Single crystals of LaTe1.9 (lanthanum telluride) have been obtained by chemical transport reactions with iodine as transport agent. LaTe1.9 adopts the CeSe1.9 structure type and crystallizes in the space group P42/n with lattice parameters a = 10.1072 (3) Å and c = 18.2874 (6) Å. The crystal structure comprises an alternating stacking of puckered [LaTe] slabs and planar [Te] layers along [001]. The planar [Te] layer is dominated by dumbbell-shaped Te2 2- anions along an isolated Te2- anion and a vacancy. The Te2 2- anions form an eight-membered ring enclosing the vacancy in the centre.

Details

Original languageEnglish
Pages (from-to)559-562
Number of pages4
JournalActa Crystallographica Section E: Crystallographic Communications
VolumeE78
Publication statusPublished - 1 Jun 2022
Peer-reviewedYes

External IDs

Scopus 85139232855
PubMed 36072144
ORCID /0000-0001-7523-9313/work/142238680

Keywords

DFG Classification of Subject Areas according to Review Boards

Subject groups, research areas, subject areas according to Destatis

Keywords

  • crystal structure, rare earth metal, superstructure, telluride, twinning