LaTe1.9: a tenfold superstructure of the ZrSSi type

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Abstract

Single crystals of LaTe1.9 (lanthanum telluride) have been obtained by chemical transport reactions with iodine as transport agent. LaTe1.9 adopts the CeSe1.9 structure type and crystallizes in the space group P42/n with lattice parameters a = 10.1072 (3) Å and c = 18.2874 (6) Å. The crystal structure comprises an alternating stacking of puckered [LaTe] slabs and planar [Te] layers along [001]. The planar [Te] layer is dominated by dumbbell-shaped Te2 2- anions along an isolated Te2- anion and a vacancy. The Te2 2- anions form an eight-membered ring enclosing the vacancy in the centre.

Details

OriginalspracheEnglisch
Seiten (von - bis)559-562
Seitenumfang4
FachzeitschriftActa Crystallographica Section E: Crystallographic Communications
JahrgangE78
PublikationsstatusVeröffentlicht - 1 Juni 2022
Peer-Review-StatusJa

Externe IDs

Scopus 85139232855
PubMed 36072144
ORCID /0000-0001-7523-9313/work/142238680

Schlagworte

DFG-Fachsystematik nach Fachkollegium

Fächergruppen, Lehr- und Forschungsbereiche, Fachgebiete nach Destatis

Schlagwörter

  • crystal structure, rare earth metal, superstructure, telluride, twinning