Intergrowth of several solid phases from the Y-Ni-B-C system in a large YNi2B2C crystal

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Torsten Weissbach - , TUD Dresden University of Technology (Author)
  • Tilmann Leisegang - , TUD Dresden University of Technology (Author)
  • Andreas Kreyssig - , TUD Dresden University of Technology, Ames Laboratory (Author)
  • Matthias Frontzek - , TUD Dresden University of Technology (Author)
  • Jens Uwe Hoffmann - , Helmholtz Centre Berlin for Materials and Energy (Author)
  • Dmitri Souptel - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Anke Köhler - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Günter Behr - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Peter Paufler - , Institute for Structural Physics, Institute of Solid State and Materials Physics (Author)
  • Dirk C. Meyer - , Junior Professorship in Nanostructural Physics (Author)

Abstract

A YNi2B2C single crystal containing traces of foreign phases was inspected by means of neutron and X-ray diffraction as well as scanning electron microscopy and X-ray spectroscopy methods. The diffraction patterns obtained from the experiments look similar to those expected for a superstructure. Nevertheless, they can be interpreted as crystallographically oriented precipitations of YB2C2 and Ni2B within the YNi2B2C crystal, formed during the cooling process. The orientation relation between the lattices was obtained from experimental neutron and X-ray data. Structure refinements of the collected X-ray data were performed by separation of the intensity data of the individual phases. Scanning electron microscopy images of the inclusions found on a polished cross section of the crystal are presented; their chemical composition was determined using wavelength-dispersive X-ray analysis.

Details

Original languageEnglish
Pages (from-to)738-746
Number of pages9
JournalJournal of applied crystallography
Volume41
Issue number4
Publication statusPublished - 2008
Peer-reviewedYes

Keywords

Keywords

  • Intermetallic compounds, Single-crystal diffraction methods