Influence of PE-CVD and PE-ALD on defect formation in permeation barrier films on PET and correlation to atomic oxygen fluence

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • F. Mitschker - , Ruhr University Bochum (Author)
  • S. Steves - , Ruhr University Bochum (Author)
  • M. Gebhard - , Ruhr University Bochum (Author)
  • M. Rudolph - , Ruhr University Bochum (Author)
  • L. Schücke - , Ruhr University Bochum (Author)
  • D. Kirchheim - , RWTH Aachen University (Author)
  • M. Jaritz - , RWTH Aachen University (Author)
  • M. Brochhagen - , Ruhr University Bochum (Author)
  • Ch Hoppe - , Paderborn University (Author)
  • R. Dahlmann - , RWTH Aachen University (Author)
  • M. Böke - , Ruhr University Bochum (Author)
  • J. Benedikt - , Ruhr University Bochum (Author)
  • I. Giner - , Paderborn University (Author)
  • T. De los Arcos - , Paderborn University (Author)
  • Ch Hopmann - , RWTH Aachen University (Author)
  • G. Grundmeier - , Paderborn University (Author)
  • A. Devi - , Ruhr University Bochum (Author)
  • P. Awakowicz - , Ruhr University Bochum (Author)

Abstract

Defects in SiOx, TiO2 and a-Si:H inorganic barrier films on PET are investigated. Visualization is achieved by reactive oxygen etching in capacitively coupled plasma that leads to the undercutting of the barrier films at defect sites, and defect densities are deduced by SEM imaging. Defect formation is analyzed as a function of absolutely quantified steady state atomic oxygen fluence during the deposition of silicon oxide films and the effect of an additional substrate bias is presented. Macro-defect densities as a function of film thickness are tracked. Barrier films with a barrier improvement of one order of magnitude exhibit macro-defect densities below 160 defects mm-2.

Details

Original languageEnglish
Article number235201
JournalJournal of Physics D: Applied Physics
Volume50
Issue number23
Publication statusPublished - 18 May 2017
Peer-reviewedYes
Externally publishedYes

Keywords

Keywords

  • atomic oxygen, barrier film, coating defects, PE-ALD, PE-CVD, polymer, silicon oxide