Improved catalytic performance of hierarchical ZSM-5 synthesized by desilication with surfactants

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Hierarchical ZSM-5 zeolites were synthesized by alkaline desilication and a surfactant induced re-assembly. Contrary to the purely alkaline desilicated zeolites a strong increase in external surface area, a narrow pore size distribution of 3-10 nm and a decreased Brönsted acidity could be achieved when using CTAB as a surfactant throughout the alkaline treatment. The hierarchical pore system and the decreased acidity lead to an improved catalyst lifetime in the methanol to hydrocarbon conversion. A further improvement could be accomplished by increasing the surfactant concentration during the desilication re-assembly preparation. Tailoring of mesopore size and specific surface area was achieved using surfactants with different chain lengths.

Details

Original languageEnglish
Pages (from-to)148-157
Number of pages10
JournalMicroporous and mesoporous materials
Volume165
Publication statusPublished - 1 Jan 2013
Peer-reviewedYes

Keywords

Keywords

  • Hierarchical ZSM-5, Improved catalytic lifetime, Mesoporous ZSM-5, Methanol to hydrocarbon, Surfactant assisted desilication

Library keywords