Improved catalytic performance of hierarchical ZSM-5 synthesized by desilication with surfactants
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Hierarchical ZSM-5 zeolites were synthesized by alkaline desilication and a surfactant induced re-assembly. Contrary to the purely alkaline desilicated zeolites a strong increase in external surface area, a narrow pore size distribution of 3-10 nm and a decreased Brönsted acidity could be achieved when using CTAB as a surfactant throughout the alkaline treatment. The hierarchical pore system and the decreased acidity lead to an improved catalyst lifetime in the methanol to hydrocarbon conversion. A further improvement could be accomplished by increasing the surfactant concentration during the desilication re-assembly preparation. Tailoring of mesopore size and specific surface area was achieved using surfactants with different chain lengths.
Details
Original language | English |
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Pages (from-to) | 148-157 |
Number of pages | 10 |
Journal | Microporous and mesoporous materials |
Volume | 165 |
Publication status | Published - 1 Jan 2013 |
Peer-reviewed | Yes |
Keywords
ASJC Scopus subject areas
Keywords
- Hierarchical ZSM-5, Improved catalytic lifetime, Mesoporous ZSM-5, Methanol to hydrocarbon, Surfactant assisted desilication